Preclinical Development

The ultimate goals of preclinical studies are to accurately model, in animals, the desired biological effect of a drug in order to predict treatment outcome in patients (efficacy), dosing and administration route (pharmacokinetic, bioavailability), and to identify and characterize all toxicities associated with a drug in order to predict adverse events (safety) for informed risk assessment.

In vivo assays are developed in accordance with the guidelines of European Union Directive 2010/63/EU on the protection of animals used for scientific purposes. Studies are performed in the Animal Facilities of the Center of Biomedical Investigation of the University of Granada (Granada, Spain).


Preclinical Development

[accordions] [accordion title=”Bioanalytical Assays”]

Standard bioanalytical method development

  • Sample preparation method development, chromatographic method development, detection method development and optimization

 

Advanced bioanalytical method development

  • Linearity and sensitivity
  • Accuracy and precision
  • Selectivity
  • Stability
  • Recovery

 

Analytical Technologies

  • High Throughput Injector CTC Pal Xt
  • 5600 QTOF Mass Spectrometer (SCIEX)
  • UPLC Cromatograph Agilent 1290 Infinity
  • Triple Quad mass Spectrometer API4000 (SCIEX)

 

Analytical tools

  • LC-MS/MS Agilent 1290-API4000 (SCIEX)
  • LC-HRMS Agilent1290-Triple TOF5600 SCIEX
  • Liquid handlers equipped with on-deck accessories; Freedom EVO, Tecan; Biomek FX and i7, Beckman, Echo® Acoustic Liquid Handling System, Beckman; EvolutionP3, PerkinElmer; and software specifically designed to automate sample preparation procedures
[/accordion] [accordion title=”ADME-tox”]

Drug absorption

  • PAMPA (Parallel artificial membrane permeability assay). Detection method: LC-MS/MS and LC-HRMS
  • Caco-2 cell permeability assay. Detection method: LC-MS/MS and LC-HRMS

 

Drug metabolism

  • CYP Inhibition: CYP1A2 / CYP2C8 / CYP2C9 / CYP2C19 / CYP2D6 / CYP3A4. Detection method: LC-MS/MS
  • CYP Induction (cryopreserved hepatocytes). Detection method: LC-MS/MS
  • CYP P450 Reaction phenotyping. Detection method: LC-MS/MS
  • Reactive metabolite assessment. Detection method: LC-MS/MS & HRMS
  • Metabolite stability (Criopreserved hepatocyte & liver microsomes) in different species (human, mouse, rat, dog, monkey, pig). Detection method: LC-HRMS
  • In vivo and in vitro metabolic profiling (Phase I and II). Comparison between species. Metabolite identification by LC-HRMS.
  • Plasma stability. Detection method: LC-MS/MS

 

Drug distribution

  • Plasma protein binding (dialysis equilibrium). Detection method: LC-MS/MS.

 

Physicochemical profiling – solutions properties

  • Kinetic solubility. Detection method: absorbance at 620 nm
  • Thermodynamic solubility. Detection method: LC-MS/MS
  • Chemical stability. Detection method: LC-MS/MS

 

Toxicity

  • Cytotoxicity: cell viability in tumor and non-tumor cells. Detection method: absorbance and HCS
  • In vitro cytotoxicity of Medical Devices (non-GLP, ISO_10993_5)
  • Genotoxicity:
    • AMES test. Detection method: visual read-out
    • Mammalian Cell Micronucleus Test (non-GLP, OECD Test Guideline 487). Detection method: HCS and in-house image analyzing App “Nucleus Finder”
  • Cardiotoxicity: ion channel activity (hERG, Nav1.5, Cav 1.2). Detection method: fluorescence (FLIPR Tetra® High-Throughput Cellular Screening System (Molecular Devices)
  • Neurotoxicity: neurotransmitter receptors: 5HT-1A. Detection method: Alphascreen®

 

[/accordion] [accordion title=”Authorization for animal studies”]
  • We prepare the project and handle the documentation for approval by the Animal Experimentation Ethics Committee (CEEA), by the Animal Experimentation Authorization Committee and by the Regional Government.
[/accordion] [accordion title=”Efficacy studies”]
  • Custom in vivo studies, different administration routes (intravenous – tail vein and retro-orbital sinus administration – oral, intra-peritoneal, subcutaneous and intramuscular), dosing regimen and readouts on demand
[/accordion] [accordion title=”Pharmacokinetic and bioavailability studies”]
  • Various administration routes: intravenous (tail vein and retro-orbital sinus administration) oral, intra-peritoneal, subcutaneous and intramuscular
  • The dosing regimen and sampling are designed according to the project needs and prior information available on the study compounds
  • Metabolite identification and profiling in vivo
  • Analysis of different matrices: blood, plasma, cerebrospinal fluid, tissues, bile, urine and feces.
  • Solid state evaluation and enhanced formulation for problematic compounds
  • Biomarker development and application within projects
  • Support of pharmacodynamic and efficacy study design
  • The relationship between concentration-time and response-time profiles varies with different targets and the position of a target in a biological pathway. The team provides analysis and interpretation of pharmacokinetic/pharmacodynamic (PKPD) relationships in support of PD.
  • Analysis of biomarkers can also be conducted at MEDINA, as it can greatly enhance the process; integration of such information in static or ideally dynamic models form the foundation for drug discovery and safety risk assessment.
  • Calculation of Pharmacokinetics parameters:
    • Half-life
    • Cmax
    • Area under curve, AUC
    • Bioavailability
    • Compartment
    • Volume of distribution, Vd
    • Clearance
    • Steady state concentration, CSS
[/accordion] [accordion title=”Toxicity studies (LD50 and MTD calculation)”]
  • Various administration routes: intravenous (tail vein and retro-orbital sinus administration) oral, intra-peritoneal, subcutaneous and intramuscular
  • Evaluation of body weights, clinical signs of toxicity and macroscopic organ toxicity
  • Acute toxicity (non-GLP, OECD Test Guideline 425) for limiting the maximal tolerated dose (MTD)
  • Short-term single dose toxicity for LD50 calculation (non-GLP, OECD Test Guideline 420)
  • Short-term repeated dose toxicity (non-GLP, OECD Test Guideline 407)
[/accordion] [/accordions]